We consider the computability and complexity of decision questions for Probabilistic Finite Automata (PFA) with sub-exponential ambiguity. We show that the emptiness problem for non-strict cut-points of polynomially ambiguous PFA remains undecidable even when the input word is over a bounded language and all PFA transition matrices are commutative. In doing so, we introduce a new technique based upon the Turakainen construction of a PFA from a Weighted Finite Automata which can be used to generate PFA of lower dimensions and of subexponential ambiguity. We also study freeness/injectivity problems for polynomially ambiguous PFA and study the border of decidability and tractability for various cases.